Alumina and Hafnia ALD Layers for a Niobium-Doped Titanium Oxide Photoanode
نویسندگان
چکیده
Niobium-doped titanium dioxide (TiO2) nanoparticles were used as a photoanode in dye-sensitized solar cells (DSCs). They showed a high photocurrent density due to their higher conductivity; however, a low open-circuit voltage was exhibited due to the back-reaction of photogenerated electrons. Atomic layer deposition is a useful technique to form a conformal ultrathin layer of Al2O3 and HfO, which act as an energy barrier to suppress the back electrons from reaching the redox medium. This resulted in an increase of the open-circuit voltage and therefore led to higher performance. HfO showed an improvement of the light-to-current conversion efficiency by 74%, higher than the 21% enhancement obtained by utilizing Al2O3 layers.
منابع مشابه
Low Temperature Gas Sensing Coatings Made Through Wet Chemical Deposition of Niobium Doped Titanium Oxide Colloid
Niobium doped titanium oxide (TiO2) colloid was synthesized to fabricate a hydrogen gas sensor layer on oxidized silicon wafer substrate. The layers were obtained using spin coating technique and then heated in air at 500 ̊C for 30 min. The doping of TiO2 led to a significant enhancement of the sensitivity of the layer especially at low operating temperature. The effect of doping was found effec...
متن کاملDioxide ( TiO 2 ) using Poly ( methyl methacrylate ) ( PMMA )
The Minnesota Nano Center’s Keller Hall facility includes an atomic layer deposition (ALD) machine that is capable of depositing uniform alumina (Al2O3), hafnium oxide (HfO2), silicon dioxide (SiO2), zinc oxide (ZnO), and titanium dioxide (TiO2). ALD works by building alternate layers on a film using two different precursor gases – one usually supplying the metallic atoms and water vapor (H2O) ...
متن کاملThe Role of Nanoscale Seed Layers on the Enhanced Performance of Niobium doped TiO2 Thin Films on Glass
Transparent conducting oxide (TCO) coatings with decreased cost and greater process or performance versatility are needed for a variety of optoelectronic applications. Among potential new TCO candidates, doped titanium dioxide is receiving particular interest. In this study, niobium-doped titania bilayer structures consisting of a nanoscale seed layer (deposited by atomic layer deposition or RF...
متن کاملUnusual Electronic Transport and Magnetism in Titanium Oxide Based Semiconductors and Metals
Title of dissertation: UNUSUAL ELECTRONIC TRANSPORT AND MAGNETISM IN TITANIUM OXIDE BASED SEMICONDUCTORS AND METALS Shixiong Zhang, Doctor of Philosophy, 2007 Dissertation directed by: Professor T. Venky Venkatesan Department of Physics The main objective of this thesis was to explore the structural, electrical, magnetic and optical properties of titanium based novel oxide thin films, such as t...
متن کاملSynthesis and Characterization of the Ti-Doped Vanadium Oxide Nanotubes
Synthesis of different kinds of nanotubes were considering after the discovery of carbon nanotubes . Lately has been noticed synthesis of vanadium oxide nanotubes. Vanadium oxide nanotubes are made of multilayer scrolls with thick walls built up from several vanadium oxide layers. This compunds be used as catalysts, molecular sieves, absorbents and energy storage devices. In this research study...
متن کامل